Octamethylcyclotetrasiloxane

Octamethylcyclotetrasiloxane
Names
Preferred IUPAC name
Octamethyl-1,3,5,7,2,4,6,8-tetroxatetrasilocane
Other names
  • D4
  • D4
  • OMCTS
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.008.307
EC Number
  • 209-136-7
UNII
  • InChI=1S/C8H24O4Si4/c1-13(2)9-14(3,4)11-16(7,8)12-15(5,6)10-13/h1-8H3
    Key: HMMGMWAXVFQUOA-UHFFFAOYSA-N
  • C[Si]1(O[Si](O[Si](O[Si](O1)(C)C)(C)C)(C)C)C
Properties
[(CH3)2SiO]4
Molar mass 296.616 g·mol−1
Density 0.956 g/mL
Melting point 17–18 °C (63–64 °F; 290–291 K)
Boiling point 175–176 °C (347–349 °F; 448–449 K)
56.2±2.5 ppb (23 °C)
log P 6.98±0.13
Vapor pressure 124.5±6.2 Pa (25 °C)
Hazards
GHS labelling:
Warning
H361f, H410 M=10
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Octamethylcyclotetrasiloxane, also called D4, is an organosilicon compound and one of a number of cyclic siloxanes (cyclomethicones). It is a colorless viscous liquid with a high boiling point. It has historically been used on a large scale in personal care products including cosmetics, hair conditioners and emollients (moisturising creams), Global production in 1993 was 136,000 tons, however it is now facing significant pressure from regulators. It is a substance of very high concern In the EU, where it was classified as a PBT and effectively banned in personal care products in 2018. The US EPA began reevaluating its risks in 2020. Replacements include branched-chain alkanes (isoparaffins).