Labyrinthite

Labyrinthite
General
CategorySilicate mineral, cyclosilicate
Formula(Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3
IMA symbolLby
Crystal systemTrigonal
Crystal classPyramidal (3)
(same H-M symbol)
Space groupR3
Unit cella = 14.24, c = 60.73 [Å] (approximated); Z = 3
Identification
ColorPink
Crystal habitanhedral grains
CleavageNone
FractureConchoidal
TenacityBrittle
Mohs scale hardness5–6
LusterVitreous
StreakWhite
DiaphaneityTransparent
Density2.88 g/cm3 (measured)
Optical propertiesUniaxial (+)
Refractive indexn0 = 1.60, ne = 1.60 (approximated)
PleochroismNone
Alters tosurface alteration to lovozerite, zirsinalite and thermonatrite
References

Labyrinthite is a very rare mineral of the eudialyte group. When compared to other species in the group, its structure is extremely complex – with over 100 sites and about 800 cations and anions – hence its name, with its complexity expressed in its chemical formula (Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3. The formula is simplified as it does not show the presence of cyclic silicate groups. Complexity of the structure results in symmetry lowering (likely due to ordering of cations) from the typical centrosymmetrical group to R3 space group. Other eudialyte-group representatives with such symmetry lowering include aqualite, oneillite, raslakite, voronkovite. Labyrinthite is the second dual-nature (both zircono- and titanosilicate) representative of the group after dualite and third with essential titanium after dualite and alluaivite.