Bis(triphenylphosphineoxide) manganese(III) chloride

manganese(III) chloride, bis(triphenylphopshine oxide)
Names
	Systematic IUPAC name trichloridobis(triphenylphopshineoxide)manganese(III)
	Other names MnCl3(OPPh3)2
Identifiers
CAS Number	61301-74-4 ;
3D model (JSmol)	Interactive image;
	InChI InChI=1S/2C18H15OP.3ClH.Mn/c219-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;/h21-15H;3*1H;/q;;;;;+3/p-3 Key: QFCMPBNNKDBSLH-UHFFFAOYSA-K;
	SMILES [Mn+3].[Cl-].[Cl-].[Cl-].O=P(c1ccccc1)(c2ccccc2)c3ccccc3.O=P(c1ccccc1)(c2ccccc2)c3ccccc3;
Properties
Chemical formula	C36H30Cl3MnO2P2
Molar mass	717.87 g·mol−1
Appearance	blue solid
Melting point	140 °C (284 °F; 413 K) (with decomposition)
Magnetic susceptibility (χ)	μeff = 4.96 μB.H. (solid-state), 4.83 μB.H. (DCM)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Bis(triphenylphosphineoxide) manganese(III) chloride is a coordination complex of manganese(III) chloride. Unlike most compounds containing "Mn(III)Cl₃", [MnCl₃(OPPh₃)₂] can be stored under normal laboratory conditions. It is a blue, paramagnetic solid.

Names


Systematic IUPAC name trichloridobis(triphenylphopshineoxide)manganese(III)
Other names MnCl₃(OPPh₃)₂
Identifiers
CAS Number	61301-74-4^Y
3D model (JSmol)	Interactive image
InChI InChI=1S/2C18H15OP.3ClH.Mn/c219-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;/h21-15H;3*1H;/q;;;;;+3/p-3 Key: QFCMPBNNKDBSLH-UHFFFAOYSA-K
SMILES [Mn+3].[Cl-].[Cl-].[Cl-].O=P(c1ccccc1)(c2ccccc2)c3ccccc3.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
Properties
Chemical formula	C₃₆H₃₀Cl₃MnO₂P₂
Molar mass	717.87 g·mol⁻¹
Appearance	blue solid
Melting point	140 °C (284 °F; 413 K) (with decomposition)
Magnetic susceptibility (χ)	μ_eff = 4.96 μ_B.H. (solid-state), 4.83 μ_B.H. (DCM)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references