(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride

[1,1'-Bis(diphenylphosphino)ferrocene]­palladium(II) dichloride
Names
IUPAC name
[1,1'-Bis(diphenylphosphino)ferrocene-κ2P,P']dichloropalladium(II)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.106.747
EC Number
  • 615-748-9
  • InChI=1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2 Y
    Key: JCWIWBWXCVGEAN-UHFFFAOYSA-L Y
  • [CH-]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3.[CH-]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pd]Cl.[Fe+2]
Properties
C34H28Cl2FeP2Pd
Molar mass 731.71 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

[1,1'‑Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is a palladium complex containing the bidentate ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf), abbreviated as [(dppf)PdCl2]. This commercially available material can be prepared by reacting dppf with a suitable nitrile complex of palladium dichloride:

dppf + PdCl2(RCN)2  (dppf)PdCl2 + 2 RCN (RCN = CH3CN or C6H5CN)

The compound is popularly used for palladium-catalyzed coupling reactions, such as the Buchwald–Hartwig amination and the reductive homocoupling of aryl halides.